Activating unreactive substrates: the role of secondary interactions

The use of secondary interactions for the activation of non-reactive substrates constitutes a relatively new and modern approach in catalysis. Activating Unreactive Substrates: The Role of Secondary Interactions is the first book to cover this new and important research topic in its entirety, revealing the links between the various disciplines. Because of its interdisciplinary approach,this reference covers a rather broad range of chemical disciplines, lending itself to the whole chemical community. A must for everyone working in the field. INDICE: Chemistry of Metalated Container Molecules The Chemistry of Super-Basic Guanidines Iron Complexes and Dioxygen Activation The Tuning of Structures and Properties of Bispidine Complexes Novel Phosphorous and Nitrogen Donor Ligands Bearing Secondary Functionalities for Applications in Homogeneous Catalysis Focussed Reactivity: Square-Pyramidal Iron Coordination Modules Regioselective Catalytic Activity of Complexes with NH, NR-Substituted Heterocyclic Carbene Ligands Functionalized Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes as Building Blocks in Metallo-Supramolecular Chemistry Monosaccharide Ligands in Organotitanium and -zirconium Chemistry Reactions of C-F Bonds with Titanocene and Zirconocene: From Secondary Interactions via Bond Cleavage to Catalysis Bis-Azines in the Coordination Sphere of Early Transition Metals Bifunctional Molecular Systems with Pendant Bis(pentafluorophenyl)boryl Groups: FromIntramolecular CH-Activation to Heterolytic Dihydrogen Splitting Selected Examples of Transition Metal Containing Polytungstates in Oxidation Catalysis From NO to Peroxide Activation by Model Fe(III) Complexes Synthetic Nitrogen Fixation with Transition-Metal Phosphine Complexes: New Developments Directed CH-Functionalizations Development of Novel Ruthenium and Iron Catalysts for Epoxidation with Hydrogen Peroxide Pentacoordinating Bis(oxazoline) Ligands with Secondary Binding Sites Flavin Photocatalysts with Substrate Binding Sites New Catalytic Cu-, Pd- and Stoichiometric Mg-, Zn-Mediated Bond Activations From Cobalt(II)-Activated Molecular Oxygen to Hydroxymethyl-Substituted Tetrahydrofurans Regiodivergent Epoxide Opening Supramolecular Containers: Host-Guest Chemistry and Reactivity Self-Assembly of Oligo Nuclear Helical Metal SupramolecularCompounds

• ISBN: 978-3-527-31823-0
• Editorial: Wiley-VCH
• Encuadernacion: Cartoné
• Páginas: 459
• Fecha Publicación: 28/01/2009
• Nº Volúmenes: 1
• Idioma: Inglés