Metal vinylidenes and allenylidenes in catalysis: from reactivity to applications in synthesis

With focus on the applications in synthesis and catalysis everything is included: ranging from polymerization to metathesis, from molecular materials to carbon rich compounds. INDICE: Preparation and stoichiometric reactivity of metal vinylidenes complexes Preparation and stoichiometric reactivity of metal allenylidenes complexes Preparation and reactivity of higher metal cumulenes Theoretical aspects of metal vinylidene and allenylidene complexes Anti-Markovnikov additions of nucleophiles to triple bonds (C-O, C-N, C-P, C-C dimerization) Group 6 metal vinylidenes in catalysis (Cr, Mo, W) Ruthenium vinylidenes and allenylidenes in catalysis for carbocyclization Allenylidene binuclear complexes in catalysis Ruthenium vinylidenes and allenylidenes precursors for olefin metathesis Metal vinylidenes in metathesis polymerization

• ISBN: 978-3-527-31892-6
• Editorial: Verlag Chemie
• Encuadernacion: Cartoné
• Páginas: 356
• Fecha Publicación: 21/05/2008
• Nº Volúmenes: 1
• Idioma: Inglés