Surface science has evolved beyond being a sub-field of chemistry or physics and has now become an underpinning science. The Third Edition of this book incorporates extensive worked solutions, as well as details on how problem solving relevant to surface science should be performed. It contextualizes the exercises and their solutions to further explicate the methods of problem solving, application of scientific principles and to deliver a deeper understanding of the field of surface science. Solutions will be accompanied by figures and/or graphs of data, as appropriate. INDICE: Acknowledgements xv1 Introduction 1I.1 Heterogeneous catalysis 2I.2 Why surfaces? 3I.3 Where are heterogeneous reactions important? 3I.4 Semiconductor processing and nanotechnology 4I.5 Other areas of relevance 5I.6 Structure of the book 51 Bulk and Surface Structure 91.1 Clean surface structure 101.2 Reconstruction and adsorbate structure 221.3 Band structure of solids 301.4The vibrations of solids 411.5 Summary of important concepts 431.6 Frontiers and challenges 441.7 Further reading 441.8 Exercises 442 Experimental Probes and Techniques 512.1 Ultrahigh vacuum 512.2 Light and electron sources 532.3 Molecular beams 572.4 Scanning probe techniques 632.5 Low energy electron diffraction (LEED) 732.6 Electron spectroscopy 802.7 Vibrational spectroscopy 952.8 Second harmonic and sum frequency generation 1032.9 Other surface analytical techniques 1052.10 Summary of important concepts 1062.11 Frontiers and challenges 1062.12 Further reading 1072.13 Exercises 1073 Chemisorption, Physisorptionand Dynamics 1153.1 Types of interactions 1153.2 Binding sites and diffusion 1163.3 Physisorption 1203.4 Non-dissociative chemisorption 1213.5 Dissociativechemisorption: H2 on a simple metal 1293.6 What determines the reactivity of metals? 1303.7 Atoms and molecules incident on a surface 1333.8 Microscopic reversibility in Ad/Desorption phenomena 1443.9 The influence of individual degrees of freedom on adsorption and desorption 1483.10 Translations, corrugation,surface atom motions 1503.11 Rotations and adsorption 1563.12 Vibrations and adsorption 1583.13 Competitive adsorption and collision induced processes 1583.14 Classification of reaction mechanisms 1613.15 Measurement of sticking coefficients 1653.16 Summary of important concepts 1683.17 Frontiers and challenges 1693.18 Further reading 1703.19 Exercises 1704 Thermodynamics and Kinetics of Adsorption and Desorption 1854.1 Thermodynamics of Ad/Desorption 1854.2 Adsorption isotherms from thermodynamics 1904.3 Lateral interactions 1934.4 Rate of desorption 1944.5 Kinetics of adsorption 2024.6 Adsorption isotherms from kinetics 2104.7 Temperature programmed desorption (TPD) 2134.8 Summary of important concepts 2214.9 Frontiers and challenges 2224.10 Further reading 2224.11 Exercises 2225 Liquid Interfaces 2295.1 Structure of the liquid/solid interface2295.2 Surface energy and surface tension 2345.3 Liquid films 2395.4 Langmuirfilms 2415.5 Langmuir-Blodgett films 2435.6 Self assembled monolayers (SAMs) 2485.7 Thermodynamics of liquid interfaces 2545.8 Electrified and charged interfaces 2575.9 Summary of important concepts 2615.10 Frontiers and challenges 2625.11 Further reading 2625.12 Exercises 2636 Heterogeneous Catalysis 2676.1 The prominence of heterogeneous reactions 2676.2 Measurement of surface kinetics and reaction mechanisms 2696.3 Haber-Bosch process 2736.4 From microscopic kinetics to catalysis 2776.5 Fischer-Tropsch synthesis and related chemistry 2836.6 The three-way automotive catalyst 2866.7 Promoters 2886.8 Poisons 2906.9 Bimetallic and bifunctional catalysts 2916.10 Rate oscillations and spatiotemporal pattern formation 2926.11 Sabatier analysis and optimal catalyst selection 2956.12 Summary of important concepts 2966.13 Frontiers and challenges 2976.14 Further reading 2986.15 Exercises 2987 Growth and Epitaxy 3057.1 Stress andstrain 3057.2 Types of interfaces 3087.3 Surface energy, surface tension and strain energy 3107.4 Growth modes 3117.5 Nucleation theory 3177.6 Growth away from equilibrium 3197.7 Techniques for growing layers 3227.8 Catalytic growth of nanotubes and nanowires 3277.9 Etching 3327.10 Summary of important concepts 3447.11 Frontiers and challenges 3447.12 Further reading 3457.13 Exercises 3458 Laser and Non-Thermal Chemistry: Photon and Electron Stimulated Chemistry and Atom Manipulation 3538.1 Photon excitation of surfaces 3548.2 Mechanisms of electron and photon stimulated processes 3668.3 Photon and electron induced chemistry at surfaces 3748.4 Charge transfer and electrochemistry 3848.5 Tip Induced process: mechanisms of atom manipulation 3978.6 Summary of important concepts 4048.7 Frontiers and challenges 4048.8 Further reading 4058.9 Exercises405References 4089 Answers to Exercises from Chapter 1. Bulk and Surface Structure 41510 Answers to Exercises from Chapter 2. Experimental Probes and Techniques 42711 Answers to Exercises from Chapter 3. Chemisorption, Physisorption and Dynamics 44512 Answers to Exercises from Chapter 4. Thermodynamics and Kinetics of Adsorption and Desorption 46513 Answers to Exercises from Chapter 5. Liquid Interfaces 48714 Answers to Exercises from Chapter 6. Heterogeneous Catalysis 49915 Answers to Exercises From Chapter 7. Growth and Epitaxy 50916 Answers to exercises from Chapter 8. Laser and Nonthermal Chemistry 515Appendix IAbbreviations and Prefixes 531Appendix II Symbols 535Appendix III Useful Mathematical Expressions 541Index 545
- ISBN: 978-1-119-99035-2
- Editorial: John Wiley & Sons
- Encuadernacion: Rústica
- Páginas: 576
- Fecha Publicación: 27/04/2012
- Nº Volúmenes: 1
- Idioma: Inglés