Organosilicon Compounds: From Theory to Synthesis to Applications

Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon-silicon bonds. This field, which includes compounds which are widely encountered in commercial products, such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last few years. Beginning with the theoretical aspects of organosilicon compounds' structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, reactive intermediates, silaaromatics, multiple bonds to silicon, and more. Next, readers will find valuable sections that explore physical and chemical properties, X-ray crystallography, 29Si NMR spectroscopy, mass spectrometry, and other methods. Finally, the work delves into applications for industrial uses and in related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistryCovers important breakthroughs in the field, along with the historically significant achievements of the pastIncludes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry)Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology INDICE: I. TheoryChapter I.1  Nonclassical Organosilicon CompoundsII. ExperimentII.1.  SynthesisII.1.1. Organosilicon Compounds of Tetracoordinate SiliconChapter II.1.1.1. Transition Metal Complexes of Silicon (excluding silylene complexes)Chapter II.1.1.2. Silicon Cages and ClustersChapter II.1.1.3.  Chiral Organosilicon CompoundsII.1.2. Organosilicon Compounds of Low-Coordinate SiliconChapter II.1.2.1. Silicon-Centered CationsChapter II.1.2.2. Silicon-Centered RadicalsChapter II.1.2.3. Silicon-Centered AnionsChapter II.1.2.4. Silylenes and Their Transition Metal ComplexesChapter II.1.2.5. Multiple Bonds to SiliconChapter II.1.2.6. Silaaromatics and Related CompoundsII.1.3. Organosilicon Compounds of Hypercoordinate SiliconChapter II.1.3.1. Penta - and Hexacoordinated Silicon (IV) CompoundsII.2.  Physico-Chemical StudiesChapter II.2.1. X-Ray Crystallography of Organosilicon CompoundsChapter II.2.2. 29Si NMR SpectroscopyChapter II.2.3. Thermochemistry of Organosilicon CompoundsChapter II.2.4. Photoelectron Spectroscopy of Organosilicon CompoundsIII.  ApplicationsChapter III.1. Hydrosilylation of the Carbon-Carbon Multiple BondsChapter III.2. PolysilanesChapter III.3. Siloxanes and SiliconesChapter III.4. Silicon-Based Dendrimers and Irregular Hyperbranched Polymers

• ISBN: 978-0-12-801981-8
• Editorial: Academic Press
• Encuadernacion: Rústica
• Páginas: 500
• Fecha Publicación: 01/08/2017
• Nº Volúmenes: 1
• Idioma: Inglés