Stereochemistry and Organic Reactions: Conformation, Configuration, Stereoelectronic Effects and Asymmetric Synthesis

Stereochemistry and Organic Reactions: Conformation, Configuration, Stereoelectronic Effects and Asymmetric Synthesis provides coverage on the stereochemistry of reactions of all mechanistic types, ranging from ionic, pericyclic and transition metal-catalyzed to radical and photochemical. Chapters cover acyclic molecules, cyclic molecules, the stereochemistry of organic reactions, the perturbation molecular orbital theory for the origin of stereoelectronic effects, and an introduction to the principles of stereoselectivity and hierarchical levels of asymmetric synthesis. Each chapter includes problems that reinforce main themes, making it valuable to students, teachers and researchers working in organic, biological and medicinal chemistry, as well as biologists, pharmacologists, polymer chemists and chemists. Presents a holistic and unified approach to stereochemical understanding and predictions, covering reactions of all mechanistic classesIncludes two background chapters on perturbation theory and stereoselective principles, along with asymmetric designsFeatures novel rules and mnemonics to delineate product stereochemistryIncludes up-to-date coverage with over 1300 selective references INDICE: Part I: Stereochemistry of Organic Molecules 1. Acyclic Molecules 1: Conformation and Symmetry 2. Acyclic Molecules 2: Configuration and Resolution 3. Cyclic Molecules: Configuration and Conformation Part II: Introduction to Stereoelectronic Effects and Stereoselective Principles 4. Perturbation Theory and Organic Reactions 5. Introduction to Stereospecificity, Stereoselectivity and Asymmetric Synthesis Part III: Stereochemistry of Organic Reactions 6. Ionic Reactions 1: Fundamental Stereochemistry 7. Ionic Reactions 2: Diastereoselectivity and Asymmetric Synthesis 8. Pericyclic Reactions 1: Basic Stereochemistry 9. Pericyclic Reactions 2: Asymmetric Synthesis 10. Transition Metal-Catalyzed Reactions: Diastereoselectivity and Asymmetric Synthesis 11. Radical Reactions: Stereochemistry and Asymmetric Synthesis 12. Photochemical Reactions: Stereochemistry and Asymmetric Synthesis

• ISBN: 978-0-12-824092-2
• Editorial: Academic Press
• Encuadernacion: Rústica
• Páginas: 600
• Fecha Publicación: 01/04/2021
• Nº Volúmenes: 1
• Idioma: Inglés