The first and ultimate guide for anyone working in transition organometallic chemistry and related fields, providing the background and practical guidance on how to efficiently work with routine research problems in NMR. The book adopts a problem-solving approach with many examples taken from recent literatureto show readers how to interpret the data. Perfect for PhD students, postdocsand other newcomers in organometallic and inorganic chemistry, as well as fororganic chemists involved in transition metal catalysis. INDICE: PREFACEWHY BOTHER?CHEMICAL SHIFTSBackground1H, 13C 15N and 31P NMRwith excursions intoHydridesAlkyl and ArylCarbonylOlefinsCarbenesPhosphinesApplicationsCOUPLING CONSTANTSBackground1J(X, Y) couplings and long-range interactionsCoupling through the metal centre:2J(31P-M-Y) and relatedApplications (and the trans influence)ROUTINE MEASURING AND RELAXATIONRelaxationHMQCOverhauser effects and NOESYCOMMENTS ON METAL CHEMICAL SHIFTSBackground103Rh195PtApplicationsEXCHANGE SPECTROSCOPYBackground2-D exchangeApplicationsDIFFUSIONBackgroundApplicationsMolecular volumesH-bondingIon pairingORGANOMETALLIC INTRODUCTIONPROBLEMSSOLUTIONS AND COMMENTSREFERENCES
- ISBN: 978-3-527-33013-3
- Editorial: Wiley-VCH
- Encuadernacion: Rústica
- Páginas: 406
- Fecha Publicación: 18/04/2012
- Nº Volúmenes: 1
- Idioma: Inglés