Functional Polymer Coatings: Principles, Methods, and Applications

Focusing on a variety of coatings, this book provides detailed discussion on preparation, novel techniques, recent developments, and design theories to present the advantages of each function and provide the tools for better product performance and properties.     Presents advantages and benefits of properties and applications of the novel  coating types     Includes chapters on specific and novel coatings, like nanocomposite, surface wettability tunable, stimuli–responsive, anti–fouling, antibacterial, self–healing, and structural coloring     Provides detailed discussion on recent developments in the field as well as current and future perspectives     Acts as a guide for polymer and materials researchers in optimizing polymer coating properties and increasing product performance INDICE: PREFACE 000 .1 Transparent Organic Inorganic Nanocomposite Coatings 1 .1.1 Introduction 1 .1.2 Fabrication Strategies 2 .1.2.1 Blending Method 2 .1.2.2 Sol Gel Process 10 .1.2.3 Intercalation Method 11 .1.3 Mechanically Enhanced Nanocomposite Clearcoats 13 .1.3.1 Solventborne Polyurethane Nanocomposite Coatings 15 .1.3.2 Waterborne Nanocomposite Clearcoats 17 .1.3.3 UV–Curable Nanocomposite Coatings 19 .1.3.4 Other Mechanically Strong Nanocomposite Coatings 26 .1.4 Optical Nanocomposite Coatings 28 .1.4.1 Transparent UV–Shielding Nanocomposite Coatings 28 .1.4.2 High Refractive Index Nanocomposite Coatings 34 .1.4.3 Transparent NIR–Shielding Nanocomposite Coatings 41 .1.5 Transparent Barrier Nanocomposite Coatings 45 .1.6 Transparent Conducting Nanocomposite Coatings 49 .1.7 Other Functional Nanocomposite Coatings 54 .1.8 Conclusions And Outlook 57 .2 Superhydrophobic and Superoleophobic Polymeric Surfaces 71 .2.1 Introduction 71 .2.2 Surface Wettability 72 .2.3 Various Approaches to Obtain Super–Repellent Surfaces 74 .2.3.1 Template–Replicating Methods 74 .2.3.2 Hierarchically Structured Particles 75 .2.3.3 LbL Deposition 78 .2.3.4 Plasma Treatment 79 .2.3.5 Chemical Vapor Deposition 81 .2.3.6 Electrospinning 83 .2.3.7 Electrochemical Polymerization 85 .2.3.8 Other Methods 86 .2.4 Applications Of Super–Repellent Polymeric Surfaces 86 .2.4.1 Self–Cleaning 86 .2.4.2 Anti–bioadhesion 87 .2.4.3 Anti–Icing 89 .2.4.4 Oil Water Separation 89 .2.5 Summary and Outlook 90 .3 Superhydrophilic and Superamphiphilic Coatings 94 .3.1 Introduction 94 .3.2 Basic Concepts of Superhydrophilicity 95 .3.3 Naturally Occurring Superhydrophilic and Superamphiphilic Surfaces 97 .3.4 Artificial Superhydrophilic Coatings 98 .3.4.1 TiO2 Coatings 98 .3.4.2 SiO2 Coatings 101 .3.5 Methods For Fabricating Superhydrophilic and Superamphiphilic Surfaces 102 .3.5.1 Sol Gel Method 102 .3.5.2 Layer–By–Layer Assembly 103 .3.5.3 Electrochemical Methods 104 .3.5.4 Electrospinning 104 .3.5.5 Etching 105 .3.5.6 Plasma Treatment 105 .3.5.7 Hydrothermal Method 106 .3.5.8 Dip Coating 107 .3.5.9 Phase Separation 107 .3.5.10 Templating Method 107 .3.6 Applications 108 .3.6.1 Self–Cleaning 108 .3.6.2 Antifogging and Antireflective Coatings 108 .3.6.3 Antifouling Properties 111 .3.6.4 Enhanced Boiling Heat Transfer 114 .3.6.5 Efficient Water Evaporation 115 .3.6.6 Switchable and Patterned Wettability Coatings 116 .3.6.7 Other Applications 117 .3.7 Commercial Coatings 117 .3.8 Conclusions and Outlook 120 .4 Self–Healing Polymeric Coatings in Smart Polymeric Coatings: Principles, Methods, and Applications 131 .4.1 Introduction 131 .4.1.1 Self–Healing Materials 132 .4.1.2 Self–Healing Polymeric Coatings 135 .4.2 Self–Healing Approaches for Functional Polymeric Coatings 136 .4.2.1 Intrinsic Healing 136 .4.2.2 Extrinsic Healing 145 .4.3 Functionalities Recovery and Possible Applications 147 .4.3.1 Surface Properties: Wettability and Anti–(bio)adhesion 147 .4.3.2 Barrier and Corrosion Protection 149 .4.3.3 Interfacial Bonding Between Dissimilar Materials 151 .4.4 Concluding Remarks and Challenges 152 .5 Stimuli–Responsive Sensing Polymeric Layers 159 .5.1 Introduction 159 .5.2 Stimuli–Responsive Soft Materials 160 .5.2.1 Thermally Responsive Polymers 161 .5.2.2 Field–Responsive Polymers 162 .5.2.3 Biologically Responsive Polymer Systems 164 .5.2.4 Multistimuli–Responsive Materials 168 .5.2.5 Stimuli–Responsive Hydrogels 171 .5.3 Sensors From Stimuli–Responsive Hydrogel Layers 172 .5.3.1 pH Sensors 174 .5.3.2 Metal Ion Sensors 175 .5.3.3 Humidity Sensors 176 .5.3.4 DNA Sensors 177 .5.3.5 Glucose Sensors 177 .5.3.6 Ionophore–Based Sensors 178 .5.4 Challenges and Opportunities 182 .6 Self–Stratifying Polymers and Coatings 193 .6.1 Introduction 193 .6.2 Basic Concepts of Self–Stratification 196 .6.2.1 Evaporation Effect 196 .6.2.2 The Surface Tension Gradient 197 .6.2.3 The Substrate–Wetting Force 199 .6.2.4 Kinetically Controlled Reactions 201 .6.3 Conclusions 210 .7 Surface–Grafted Polymer Coatings: Preparation, Characterization, and Antifouling Behavior 213 .7.1 Introduction 213 .7.2 Surface–Grafting Methods 214 .7.2.1 Grafting–From Method 214 .7.2.2 Grafting–To Method 215 .7.3 Behavior of Surface–Grafted Polymers 217 .7.3.1 Conformation of Grafted Chains 217 .7.3.2 Chain Migration 218 .7.4 Characterization Techniques 219 .7.4.1 Ellipsometry 219 .7.4.2 Contact Angle 219 .7.4.3 X–ray Photoelectron Spectroscopy 220 .7.4.4 Scanning Probe Microscopies 221 .7.5 Antifouling Coatings 222 .7.5.1 Surface–Grafted PEG 223 .7.5.2 Surface–Grafted Zwitterionic Polymers 224 .7.6 Summary 225 .8 Partially Fluorinated Coatings by Surface–Initiated Ring–Opening Metathesis Polymerization 234 .8.1 Basic Concepts 234 .8.2 Surface Chemistry 236 .8.3 Kinetics of Film Growth 237 .8.4 Surface Energy of Pnbfn Films 238 .8.5 Micromolding Sip 240 .8.6 Conclusions and Outlook 242 .9 Fabrication and Application of Structural Color Coatings 245 .9.1 Introduction 245 .9.2 General Methods of Colloidal Assembly 247 .9.2.1 Flow–Induced Deposition 247 .9.2.2 Field–Induced Deposition 252 .9.3 Colloidal Assembly of Soft Polymer Spheres 255 .9.4 Uses of Structural Colors 260 .9.4.1 Photonic Paper 260 .9.4.2 Coloring and Protection of Substrates 262 .9.4.3 Color Responses 263 .9.4.4 Structural Color Coatings with Lotus Effects and Superhydrophilicity 267 .9.4.5 Structural Color as Effect Pigments 268 .9.5 Conclusions and Outlook 268 .10 Antibacterial Polymers and Coatings 273 .10.1 Introduction 273 .10.2 Basic Concepts 274 .10.2.1 Coatings that Resist Adhesion 275 .10.2.2 Coatings that Release Toxins 275 .10.3 Polymers And Antimicrobial Coating Binders 276 .10.3.1 Polymeric Coatings with QA Groups 276 .10.3.2 Polymers with Quaternary Phosphonium Groups 277 .10.3.3 Norfloxacin–Containing Polymers 279 .10.3.4 Polymeric N–Halamines 281 .10.4 Addition of Inorganic Particles 282 .10.4.1 Titanium Dioxide 282 .10.4.2 Zinc Oxide 283 .10.4.3 Silver Compounds 283 .10.5 Conclusions And Outlook 285 .11 Novel Marine Antifouling Coatings: Antifouling Principles and Fabrication Methods 288 .11.1 Introduction 288 .11.2 Marine Biofouling 289 .11.3 Enzyme–Based Coatings 292 .11.4 Fouling Release Coatings 294 .11.4.1 Principles of FR Coatings 294 .11.4.2 Hybrid Silicone–Based FR Coatings 296 .11.4.3 Fluoropolymer–Based FR Coatings 297 .11.5 Nonfouling Coatings 297 .11.5.1 Principles of NF Coatings 298 .11.5.2 PEG–Based NF Coatings 299 .11.5.3 Poly(Zwitterionic) NF Coatings 303 .11.5.4 Other Hydrophilic NF Materials 305 .11.6 Bioinspired Micro–Topographical Surfaces 308 .11.6.1 AF Principles of Bioinspired Microtopographical Surfaces 308 .11.6.2 Approaches to the Production of AF Coatings with Surface Topographies 312 .11.7 Amphiphilic Nanostructured Coatings 314 .11.7.1 Principles of Amphiphilic Nanostructured Coatings 315 .11.7.2 PEG–Fluoropolymers Amphiphilic Coatings 317 .11.7.3 Other Amphiphilic AF Polymers 321 .11.7.4 Characterization Techniques 321 .11.8 Summary 323 .GLOSSARY 000 .INDEX 000

• ISBN: 978-1-118-51070-4
• Editorial: Wiley–Blackwell
• Encuadernacion: Cartoné
• Páginas: 368
• Fecha Publicación: 28/07/2015
• Nº Volúmenes: 1
• Idioma: Inglés