Raman Spectroscopy and its Application in Nanostructures is an original and timely contribution to a very active area of physics and materials science research. This book presents the theoretical and experimental phenomena of Raman spectroscopy, with specialized discussions on the physical fundamentals, new developments and main features in low-dimensional systems of Raman spectroscopy.In recent years physicists, materials scientists and chemists have devoted increasing attention to low-dimensional systems and as Raman spectroscopy can be used to study and analyse such materials as carbon nanotubes, quantum wells, silicon nanowires, etc., it is fast becoming one of the most powerful and sensitive experimental techniques to characterize the qualities of such nanostructures.Recent scientific and technological developments have resulted in the applications of Raman spectroscopy to expand. These developments are vital in providing information for a very broad field of applications: for example in microelectronics, biology, forensics and archaeology. Thus, this book not only introduces these important new branches of Raman spectroscopy from both a theoretical and practical view point, but the resulting effects are fully explored andrelevant representative models of Raman spectra are described in-depth with the inclusion of theoretical calculations, when appropriate. INDICE: Preface ixAcknowledgements xiiiPart I Fundamentals of Raman Spectroscopy 11 Basic Knowledge of Raman Spectroscopy 31.1 Spectrum and Spectroscopy31.2 Scattering and Raman Scattering 51.3 Fundamental Features of Raman Scattering Spectra 91.4 Discovery of the Raman Scattering Effects and Observation of the First Raman Spectrum 101.5 Historical Development of Raman Spectroscopy 13References 162 Fundamental Theory of Light Scattering 192.1 Description of Scattering 202.2 Macroscopic Theory of Light Scattering 262.3 Microscopic Theory of Light Scattering 39References 453 Experimental Foundation of Raman Spectroscopy 473.1 Generality of Raman Spectral Measurements 473.2 Experimental Apparatus 563.3 Main Performance Parameters of Raman Spectrometers 793.4 Experimental Measurements 833.5 Data Processing of Recorded Raman Spectra 883.6 A Typical Example of Vibration Raman Spectra - Raman Spectrum of CCl4 943.7 Interference Spectrometer and Fourier Transform Optics 97References 1044 Introduction to Modern Raman Spectroscopy I-New Raman Spectroscopic Branch Classified Based on Spectral Features 1054.1 Non-visible Excited Raman Spectroscopy 1064.2 Resonant Raman Spectroscopy (RRS) 1064.3 High-Order/Multiple-Phonon Raman Spectroscopy (MPRS) 1104.4 Raman Spectroscopy under Extreme Conditions 1144.5 Polarized Raman Spectroscopy (PRS) 1154.6 Time-Resolved (Transient) Raman Spectroscopy(TRRS) 1164.7 Space-Resolved Micro-Raman Spectroscopy and Raman Microscopy 1184.8 Surface-enhanced Raman Spectroscopy (SERS) 1194.9 Near-Field Raman Spectroscopy (NFRS) 1214.10 Tip-enhanced Raman Spectroscopy (TERS) 1304.11 Non-linear and Coherent Raman Spectroscopy (NLRS) 1364.12 Coherent Anti-Stokes Raman Scattering (CARS) 1384.13 Stimulated Raman Scattering (SRS) 145References 1505 Introduction to Modern Raman Spectroscopy II-New Raman Spectroscopic Branch Classified Based on Applied Objects 1535.1 Common Spectroscopic Basis Related to the Study and Application of Raman Spectroscopy 1535.2 Chemistry Raman Spectroscopy 1585.3 Condensed Matter Raman Spectroscopy 1605.4 Biological and MedicalRaman Spectroscopy 1665.5 Geology and Mineralogy Raman Spectroscopy 1755.6 Art and Archeology Raman Spectroscopy 1775.7 Industry Raman Spectroscopy 1785.8 Raman Spectroscopy in National Security and Judicature 181References 182Part II Study of Nanostructures by Raman Spectroscopy 1856 General Knowledge of Nanostructures 1876.1 Nanostructure, Characteristic Length, and Dimension 1876.2 Nanomaterials 1886.3 Properties of Nanostructures 1906.4 Finite Size and Specific Surface 1926.5 The Study of Nanostructure 196References 1977 Theoretical Fundamentals of Raman Scattering in Solids 1997.1 General Knowledge of Lattice Dynamics 2007.2 Microscopic Model of Lattice Dynamics 2137.3 Macroscopic Model of Lattice Dynamics 2227.4 Lattice Dynamics of Amorphous Matter 2297.5 Raman Scattering Theories in Solids 230References 2468 Theoretical Fundamentals of Raman Scattering in Nanostructures 2498.1 Superlattices 2508.2 Nanostructure Materials 2648.3 Micro-Crystal Models 2838.4 Amorphous Feature and PDOS Expression of Nanostructure Raman Spectra 2968.5 First-Principles/ab initio Calculationof Nanostructure Raman Spectra 298References 3069 Routine Raman Spectra of Nanostructures 3099.1 Characteristic Raman Spectra of Semiconductor Superlattices 3109.2 Characteristic Raman Spectra of Nanosilicon 3189.3 Characteristic Raman Spectra of Nanocarbons 3259.4 Characteristic Raman Spectra of Polar Nano-Semiconductors 3379.5 Multiple-Phonon Raman Spectra 3439.6 Anti-Stokes Raman Spectra 352References 35710 Raman Spectroscopy of Nanostructures with Exciting Laser Features 36110.1 Raman Spectra with Changing of Exciting Light Wavelengths- Resonant Raman Spectra 36110.2 Raman Spectra with Exciting Laser Polarization 37310.3 Raman Spectra with Exciting Laser Intensity 378References 39211 Raman Spectra with Samples of Nanostructures 39511.1 Effects of Sample Sizes on Raman Spectra of Nanostructures 39511.2 Effects of Sample Shapes on Raman Spectra in Nanostructures 40911.3 Effects of Sample Component and Micro-structure on Raman Spectra in Nanostructures 413References 41712 Electron-Phonon Interactions in Raman Spectroscopy of Nanostructures 41912.1 Abnormal Raman Spectral Features in Nanostructures 41912.2 Origin of No FSE on Phonons 42012.3 Fr€ohlich Interaction in Nanostructures 42312.4 Theoretical Raman Spectra of Non-polarand Polar Nano-Semiconductors 42412.5 Amorphous Feature of Nanocrystal Raman Spectra of No FSE on Phonons and the Breaking of Translation Symmetry in Nano-Semiconductors 426References 428Appendices 429Appendix I Electromagnetic Wavesand Lasers 429I.1 Electromagnetic Wavelength 429I.2 Laser Types 430I.3 Laser Lines and Ionic/Atomic Lines of Gas Lasers used Commonly in Raman Spectroscopy432Appendix II Standard Spectral Lines 438II.1 Spectral Lines of Mercury Lampin Visible Range 438II.2 Standard Lines of Neon Spectral Lamp 439Appendix IIIRaman Tensors 442III.1 Raman Tensors and Symmetric Attributes 442III.2 Applications of Raman Tensors 447Appendix IV Constitution, Polarity, and Symmetry Structure of Crystals 452IV.1 Constitution, Polarity, and Crystal Structure of Crystals 452IV.2 Syngony and its Basic Vector, Bravais Lattice, and Point GroupSymmetry 455Appendix V Brillouin Zones, Vibration Modes, and Raman Spectra ofTypical Ordinary and Semiconducting Crystals 458V.1 Brillouin Zones and Symmetrical Points of Cubic System 458V.2 Vibrational Modes and their Symmetries ofSeveral Crystals 460V.3 Structures, Symmetries, and Raman Spectra of Several Semiconducting Crystals 461Appendix VI Physical Parameters, Constants, and Units 466VI.1 Periodic Table of the Elements 466VI.2 Electronic Structure of Atoms 467VI.3 Common Physical Constant and the Performance Parameters of Optical Glass 470References 472Index 473
- ISBN: 978-1-119-96165-9
- Editorial: John Wiley & Sons
- Encuadernacion: Rústica
- Páginas: 496
- Fecha Publicación: 15/03/2012
- Nº Volúmenes: 1
- Idioma: Inglés